Catalytic asymmetric deprotonation of phosphine boranes and sulfides as a route to P-stereogenic compounds |
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| Authors: | Gammon Jonathan J Canipa Steven J O'Brien Peter Kelly Brian Taylor Sven |
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| Affiliation: | Department of Chemistry, University of York, Heslington, York, UK. |
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| Abstract: | A comparison between phosphine boranes and sulfides in their catalytic asymmetric deprotonation using organolithiums and sub-stoichiometric amounts of (-)-sparteine has revealed superior catalytic efficiency in the phosphine sulfide deprotonation. |
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