Acyl palladium species in synthesis: single-step synthesis of alpha,beta-unsaturated ketones from acid chlorides |
| |
| Authors: | Cox Russell J Evitt Andrew S |
| |
| Affiliation: | School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK. r.j.cox@bris.ac.uk |
| |
| Abstract: | Conditions are reported for the facile, one-pot synthesis of alpha,beta-unsaturated ketones via the palladium-catalysed cross-coupling of acyl chlorides with hydrozirconated acetylenes, and its use in the 2-step synthesis of D-5-O-benzyl deoxyxylulose. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
