Synthesis and structure of the chiral palladium-fullerene C<sub>60</sub> and C<sub>70</sub> complexes with enantiomeric ligand 2,2′,5,5′-tetramethyl-4,4′-bis(diphenylphosphino)-3,3′-bithiophene [(−)tetraMe-BITIOP]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Synthesis and structure of the chiral palladium-fullerene C₆₀ and C₇₀ complexes with enantiomeric ligand 2,2′,5,5′-tetramethyl-4,4′-bis(diphenylphosphino)-3,3′-bithiophene [(−)tetraMe-BITIOP]

Authors:	Vasily V Bashilov Pavel V Petrovskii Mara Sada Gianni Zotti

Institution:	^a “Nesmeyanov” Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, 119991 Moscow, Russian Federation ^b Universita di Milano, Dipartamento Chimica Organica e Industriale, via Golgi 19, 20133 Milano, Italia ^c Universita dell’Insubria, Dipartamento Chimiche, Fisiche e Mathematiche, via Valleggio 11, 22100, Como, Italia ^d Istituto CNR per l’Energetica e le Interfasi, Corso Stati Uniti 4, 35127 Padova, Italia

Abstract:	η²-Fullerene (C₆₀ and C₇₀) palladium optically active complexes with the axially chiral enantiomeric ligand of bithienyl series, (−)tetraMe-BITIOP], have been synthesized and investigated by ³¹P-{¹H} NMR, electronic spectroscopy, CD spectroscopy, cyclic voltammetry and by single crystal X-ray diffraction.

Keywords:	[60]fullerene [70]fullerene Palladium-fullerene complexes Optical activity Axial chirality (&minus )tetraMe-BITIOP Circular dichroism NMR electronic spectroscopy X-ray structure Cyclic voltammetry
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