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Cyclometalated platinum complexes: High-yield synthesis, characterization, and a crystal structure |
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| Authors: | Jian-Yang Cho Jennifer Li Stephen Barlow |
| Affiliation: | a Center for Organic Photonics and Electronics and School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA b Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia c Department of Natural Sciences, New Mexico Highlands University, Las Vegas, NM 87701, USA |
| Abstract: | The one-pot reaction of K2PtCl4 and various 2-arylpyridines, HC∧N, in a 3:1 (v/v) mixture of 2-ethoxyethanol and H2O at 80 °C for 16 h affords cyclometalated platinum complexes, Pt(C∧N)(HC∧N)(Cl), in high yield. These have been fully characterized and, in one case, the X-ray structure has been determined. |
| Keywords: | Cyclometalated metal complexes Platinum Phosphorescent 2-Aryl-pyridine Crystal structure |
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