Luminescent palladium complexes containing thioamide-based SCS pincer ligands |
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| Authors: | Michinori Akaiwa Hiroki Fukumoto Takakazu Yamamoto |
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| Institution: | Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan |
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| Abstract: | Thioamide-based tridentate ligands, 1,3-benzenedicarbothioamides (1a-c), were used to afford pincer palladium(II) complexes (Pd(1-H)Cl, 2a-c) with η3-S,C,S type coordination. The complexes exhibit strong emission in a glassy frozen state as well as in the solid state. The decay lifetime of the emission from the complexes is in a range of 8-9 × 10−5 s, which is indicative of phosphorescent emission. |
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| Keywords: | Palladium Pincer ligand Thioamide Luminescence |
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