A new method for the synthesis of acyltitanium complexes and their application to copper-mediated acylmetallation of carbon-carbon multiple bonds in aqueous media |
| |
| Authors: | Han Zhenfu Fujioka Takuma Usugi Shin-Ichi Yorimitsu Hideki Shinokubo Hiroshi Oshima Koichiro |
| |
| Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan. |
| |
| Abstract: | Treatment of alpha, beta-unsaturated carbonyl compounds or methyl propargyl ether with acylchlorobis(cyclopentadienyl)titanium in the presence of triethylamine and a copper salt in aqueous THF resulted in acylation of the carbon-carbon multiple bond, yielding the corresponding 1,4-diketones in good yields. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
