| Hydrothermal Synthesis and Structure of[{Mo_8V_4O_(36)(VO_4)(VO)_2}n]~(7n-)Bi-capped α-Keggin Fragments Linked to a Chain |
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| 引用本文： | LUAN Guo-you,HAN Zheng-bo,WANG En-bo* *LU Ying,LI Yang-guang and HU Chang-wen (Department of Chemistry,Northeast Normal University,Changchun 130024,P. R. China)HU Ning-hai and JIA Heng-qing(Changchun Institute of Applied Chemistry,Chinese Academ. Hydrothermal Synthesis and Structure of[{Mo_8V_4O_(36)(VO_4)(VO)_2}n]~(7n-)Bi-capped α-Keggin Fragments Linked to a Chain[J]. 高等学校化学研究, 2001, 17(4) |
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| 作者姓名： | LUAN Guo-you HAN Zheng-bo WANG En-bo* *LU Ying LI Yang-guang and HU Chang-wen (Department of Chemistry Northeast Normal University Changchun 130024 P. R. China)HU Ning-hai and JIA Heng-qing(Changchun Institute of Applied Chemistry Chinese Academ |
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| 作者单位： | LUAN Guo-you，HAN Zheng-bo，WANG En-bo* *LU Ying，LI Yang-guang and HU Chang-wen (Department of Chemistry，Northeast Normal University，Changchun 130024，P. R. China |
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| 基金项目： | National Natural Science Foundation of China. |
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| 摘 要： | The title compound, (H2en)3H3O{Mo8V4O36(VO4) (VO)2} ?4H2O, was hydrothermally synthesized and structurally characterized by means of IR, ESR spectrum and single crystal X-ray diffraction. It crystallized in a monoclinic system with space group P21/c, a=1. 980 4(4) nm, 6=2. 063 4(4) nm, c=l. 192 0(2) nm, =94. 76(3)?and deep black colour. The compound contains V-centered bi-capped a-Keggin fragments {Mo8V7O42} that are linked together by edge-shared units V O5 via V桹梀 bonds, forming a chain.
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Hydrothermal Synthesis and Structure of [{Mo8V4O36 (VO4) (VO)2 }n]7n-Bi-capped α-Keggin Fragments Linked to a Chain |
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| LUAN Guo-you,HAN Zheng-bo,WANG En-bo,LU Ying,Li yang-guang,HU Chang-wen,HU Ning-Hai,JIA Heng-qing. Hydrothermal Synthesis and Structure of [{Mo8V4O36 (VO4) (VO)2 }n]7n-Bi-capped α-Keggin Fragments Linked to a Chain[J]. Chemical Research in Chinese University, 2001, 17(4) |
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| Authors: | LUAN Guo-you HAN Zheng-bo WANG En-bo LU Ying Li yang-guang HU Chang-wen HU Ning-Hai JIA Heng-qing |
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| Abstract: | The title compound, (H2en) 3H3O { MosV4O36 (VO4) (VO) 2 } · 4H2O, was hydrothermally synthesized and structurally characterized by means of IR, ESR spectrum and single crystal X-ray diffraction. It crystallized in a monoclinic system with space group P21/c, a= 1. 980 4(4)nm, b＝2. 063 4(4) nm, c=1. 192 0(2) nm, β=94. 76(3)°and deep black colour. The compound contains V-centered bi-capped a-Keggin fragments { MosV7O42 } that are linked together by edge-shared units V ⅣO5 via V-O-V bonds, forming a chain. |
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| Keywords: | Keywords Hydrothermal synthesis Bi-capped a-Keggin compound Monoclinic system Polyanion |
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