Key Laboratory for Colloid and Inter face Chemistry of the Educational Ministry,Department of Chemistry,Shandong University,Jinan 250100,P. R. China; Department of Chemistry,The
基金项目:
Educational Ministry of China, Natural Science Foundation of China (Grant No. 29701002, 29992590-4), the Visiting Scholar Foun
摘 要:
IntroductionThe homoleptic sandwich~type porphyrinato and phthalocyaninato metal complexesRE (P) z and RE2 (P) 3 (RE =rare earth 1 P = Por or Pc) have been intensively studied over sev-eral decades due to their potential application in non-linear optical (NLO) materials, molecu-lar electronic and magnetic ..te.i.l.L1--l6j.The double-deckers have also aroused a growing interest as structural and spectroscopicsynthetic models for the dimmer of bacteriochlorophyl1 molecules in bacterial pho…