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Optimizedprocedure for clay pillaring with aluminum species used in depollution
Authors:Denisa Nistor  P. I. Dron  Georgiana G. Surpăţeanu  Ilie Siminiceanu  N. D. Miron  A. Azzouz
Affiliation:(1) Département I.P.A., Faculté d’Ingénierie, Université de Bacău, Bacău, Romania, 5500, 157,Rue Mărăşeşti;(2) Département de Chimie Organique et Biochimie, Faculté de Chimie, Université ‘Al. I. Cuza’, Iaşi, Romania, 6600, 11, Boulevard Carol I;(3) Département Technologies Anorganiques, Faculté de Génie Industrielle, Université Technique Gh Asachi, Iaşi, Romania, 6600, 71 Bvd Dimitrie Mangeron
Abstract:
This study presents the improved method of smectite type clays pillaring, using aluminum salts. To achieve this goal, natural clay with a percentage of more than 95% montmorillonite was used. In order to analyze the pillaring process, a thermal procedure was used (thermal programmed desorption). The results of the pillaring process show that a controlled distance between the foliar band structures as long as 18·10–10 m can be obtained. The clays modified by pillaring can be used as molecular sieves in microfiltration processes or as agents in residual water chemical depolluting processes. They also have zeolite properties which make them reusable.
Keywords:clay pillaring  depollution  programmed thermodesorption
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