Reductive Cleavage of S-S Bond by Sm/NiCl_2 or Sm/NiCl_2·6H_2O System: A New Method for the Preparation of Thiolesters 期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Reductive Cleavage of S-S Bond by Sm/NiCl_2 or Sm/NiCl_2·6H_2O System: A New Method for the Preparation of Thiolesters

作者姓名：	Hua Yue WU Red Er CHEN Yong Min ZHANG

作者单位：	Hua Yue WU; Red Er CHEN; Yong Min ZHANG(Department of Cheniistry，Wenzhou Normal College，Wenzhou，325000)(Departnieni of Chemistry. Zhejiang University at Xixi Campus，Hangzhou，310028)

摘要：	Theroleofthiolestersasacylatingagentsinbiochemicalprocessesandtheirhighreactivitywithvariousnucleophiles,hasmadethemanattractivesyntheticintermediateinorganicsynthesis'-'.Manynewmethodshavebeendevelopedforthepreparationofthiolestersinrecentyears'-",forexample,thereactionbetweensodiumthiobenzoateandarenediazoniumtetrafluoroborates',tTedrientofnitrosoamidesornitroamideswithmercaptansinthepresenceofsodiumhydride',thecobaltcarbonylcatalyzedcarbonylationofmercaptans'andthecobaltchloridecatalyzedcou…
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