Synthesis and Crystal Structure of 2,4-Diiodo-6-[(2-morpholin-4-yl-ethylimino)-methyl]-phenolato-zinc(II) |
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| Authors: | Suo-Ping Xu Peng-Cheng Lv Rui-Qin Fang Lei Shi Hai-Liang Zhu |
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| Institution: | 1.Key Laboratory of Anhui Educational Department,Anhui University of Technology,Maanshan,People’s Republic of China;2.School of Chemistry and Chemical Engineering,Xuzhou Normal University,Xuzhou,People’s Republic of China;3.School of Life Sciences,Nanjing University,Nanjing,People’s Republic of China |
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| Abstract: | Abstract One new complex, 2,4-Diiodo-6-(2-morpholin-4-yl-ethylimino)- methyl]- phenolato-zinc(II) has been designed and synthesized.
The structure was determined by UV, IR and single X-ray crystallography study. The title complex C26H30O4N4I4Zn crystallizes in the triclinic space group P − 1 with the cell parameters a = 9.938(2) ?, b = 11.937(2) ?, c = 14.527(3) ?, α = 87.14(3)°, β = 79.03(3)°, γ = 76.20(3)°, V = 1565.1(5) ?3 and Z = 2. The central zinc(II) is four coordinate and bonds to two nitrogen atoms and two oxygen atoms from two 3,5-diiodosalicylaldehyde-2-
morpholinoethylamine Schiff bases. The complex is linked into a column by weak intermolecular interactions. |
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