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高压下碱卤晶体的三参量等温状态方程
引用本文:严祖同.高压下碱卤晶体的三参量等温状态方程[J].高压物理学报,2006,20(1):51-55.
作者姓名:严祖同
作者单位:安徽师范大学物理与电子信息学院,安徽芜湖,241000
基金项目:安徽省省级重点学科基金项目(20022DXK),安徽省教育厅自然科学基金(2001KJ110)
摘    要: 由等温体积弹性模量的定义及其与压强关系的假设出发,导出了一个新的适用于高压下碱卤晶体的三参量等温状态方程。计算了室温下NaCl晶体在0~30 GPa压强范围内、CsCl晶体在0~40 GPa压强范围内的相对体积以及NaCl晶体在0~30 GPa压强范围内的等温体积弹性模量,计算结果与实验值一致。对等温体积弹性模量及其对压强的一阶、二阶导数与压强的关系进行了讨论,指出压强趋于无穷大时的等温体积弹性模量是常数。

关 键 词:状态方程  等温体积弹性模量  NaCl晶体  CsCl晶体  高压
文章编号:1000-5773(2006)01-0051-05
收稿时间:2004-10-21
修稿时间:2004-11-19

An Isothermal Three-Parameter Equation of State Applied to Alkali Halide Crystals under High Pressures
YAN Zu-Tong.An Isothermal Three-Parameter Equation of State Applied to Alkali Halide Crystals under High Pressures[J].Chinese Journal of High Pressure Physics,2006,20(1):51-55.
Authors:YAN Zu-Tong
Institution:College of Physics and Electronic Information ,Anhui Normal University ,Wuhu 241000,China
Abstract:From the definition of isothermal bulk modulus and an assumption of its relationship with the pressure, an isothermal three-parameter equation of state has been proposed, which is found to be applicable at high pressure. The proposed equation of state has been used to compute the pressure-volume behavior of NaCl crystal in the pressure range 0~30 GPa and CsCl crystal in the pressure range 0~40 GPa. The isothermal bulk modulus in the pressure range 0~30 GPa of NaCl crystal were also calculated. The results are in very good agreement with the experimental data. The pressure dependence of the isothermal bulk modulus BT and its first- and second-order pressure derivative are discussed, and the bulk modulus increases continuously with the increasing pressure and has a finite value as p→∞.
Keywords:isothermal equation of state  isothermal bulk modulus  NaCl crystal  CsCl crystal  high pressure
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