The first ammonium aromatic diselenoates: stable heavy congeners of aromatic carboxylic acid salts |
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| Authors: | Tani Kazuyasu Murai Toshiaki Kato Shinzi |
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| Affiliation: | Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-1193, Japan. |
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| Abstract: | Ammonium aromatic diselenoates were synthesized by reacting aromatic diselenoic acid 2-(trimethylsilyl)ethyl esters derived from aluminum 2-(trimethylsilyl)ethyl selenolate with aromatic selenoic acid O-methyl esters with ammonium fluorides. The results of molecular structure analysis and NMR studies of ammonium salts supported the double-bond character between the carbon atom and selenium atoms. |
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