35Cl NQR spectra of bis(chlorobenzene)chromium(0) and bis(chlorobenzene) chromium(I) iodide |
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Authors: | G K Semin E V Bryukhova D N Kravtsov L P Yur'eva N N Zaitseva I A Uralets |
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Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusion A study was carried out on the35Cl NQR spectra of bis(chlorobenzene)chromium(O) and bis(chlorobenzene)chromium(I) iodide. The coordination of chlorobenzene with the charged ClC6H6Cr+ fragment leads to a sharp decrease in electron density. This effect is significantly greater than that resulting from the coordination of chlorobenzene with the ClC6H5Cr group in neutral bis(chlorobenzene)chromium.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2801–2803, December, 1986. |
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