Comparisons of <Emphasis Type="Italic">n</Emphasis>th-order kinetic algorithms and kinetic model simulation on HMX by DSC tests |
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| Authors: | Chun-Ping Lin Yi-Ming Chang Jo-Ming Tseng Chi-Min Shu |
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| Institution: | (1) Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology (NYUST), 123, University Rd., Sec. 3, Douliou, Yunlin, 64002, Taiwan, ROC;(2) Institute of Safety and Disaster Prevention Technology, Central Taiwan University of Science and Technology, 666, Buzih Rd., Beitun District, Taichung, 40601, Taiwan, ROC;(3) Department of Safety, Health, and Environmental Engineering, NYUST, 123, University Rd., Sec. 3, Douliou, Yunlin, 64002, Taiwan, ROC; |
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| Abstract: | Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) is a typical highly energetic material that has been widely used in
national defense industries since the 1940s. The aim of this study was to establish a reaction kinetic model on thermal decomposition
properties via differential scanning calorimetry (DSC) by well-known kinetic equations and kinetic model simulation. Furthermore,
the aim also was to compare kinetic algorithms for thermal decomposition energy parameters under various conditions. Experimental
results highly depended on the reliability of the kinetic concept applied, which is essentially defined by the proper choice
of a mathematical model of a reaction. In addition, the correctness of the methods is used for kinetics evaluation. |
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