Short-lived chemical species of57Fe in57Co-labelled Co/IO3/2 studied by time-resolved emission Mössbauer spectroscopy |
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Authors: | Y. Watanabe K. Endo H. Sano |
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Affiliation: | (1) Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Fukasawa, Setagaya, 158 Tokyo, Japan |
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Abstract: | Time resolved Mössbauer spectra were measured for57Co-labelled Co/IO3/2 using a delayed coincidence technique. A life-time for unstable57Fe(II)-species formed through EC-decay was estimated to be 43±5 ns at room temperature and the initial distribution of57Fe(II)/57Fe(III) at 14.4 keV nuclear level to be 0.47±0.13. The results are discussed in terms of electron transfer from the decayed57Fe(II) atoms to iodate ions. |
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