Thermodynamic characteristics of the thermal polymerization of perfluoropropylvinyl ether at high pressures |
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Authors: | A A Zharov I B Konovalova |
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Institution: | 1.Zelinsky Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | The limiting polymerization temperatures of PFPVE at pressures 5.28–10.56 kbar (T c = 200°C at 7.04 kbar and T c = 240°C at 10.56 kbar) are measured. The volume of reaction ΔV and enthalpy of polymerization ΔH are determined. |
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