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Temperature-programmed desorption of water and ammonia on sulphated zirconia catalysts for measuring their strong acidity and acidity distribution
Authors:Vasant R. Choudhary and Abhijeet J. Karkamkar
Affiliation:(1) Chemical Engineering Division, National Chemical Laboratory, 411 008 Pune, India
Abstract:Temperature-programmed desorption (TPD) of water and ammonia over ZrO2 and sulphated ZrO2 prepared by different methods has been investigated for measuring strong acidity and acidity distribution on sulphated zirconia-type solid super-acid catalysts. The TPD of water provides a simple reliable method for this purpose because of the high stability of water molecules under redox conditions
Keywords:Temperature-programmed desorption  sulphated zirconia catalysts  acid catalysts  acidity distribution
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