Synthesis of functionalized fluorine-containing trimethylsilylcarbodiimides |
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| Authors: | D. V. Romanov T. V. Strelkova Yu. A. Strelenko N. V. Vasil'ev |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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| Abstract: | New functionalized polyfluorinated carbodiimides RFN=C=NSiMe3 were prepared by the reactions of bis(trimethylsilyl)carbodiimide with electrophilic reagents. The structures of the resulting compounds were confirmed by1H,13C,29Si,14N,15N, and17O NMR spectroscopy. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 775–777, April, 1999. |
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| Keywords: | polyfluorinated carbodiimides substitution and addition reactions |
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