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Dynamics of three-body half collisions: Ultraviolet and visible photodissociation of s-tetrazine
Authors:James H. Glownia  Stephen J. Riley
Affiliation:Department of Chemistry, Yale University, New Haven, Connecticut 06520, USA
Abstract:Ultraviolet (266 nm) and visible (532 nm) photodissociation of collision-free s-tetrazine show asymmetric dynamics with production of one translationally cool and one translationally hot HCN molecule. Furthermore, visible and ultraviolet dynamics are nearly identical, arguing that two-photon excitation is necessary for photodissociation in the visible.
Keywords:On leave   present address Radiation Physics Division   National Bureau of Standards   Washington   D.C. 20234   USA.
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