Dynamics of three-body half collisions: Ultraviolet and visible photodissociation of s-tetrazine |
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Authors: | James H. Glownia Stephen J. Riley |
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Affiliation: | Department of Chemistry, Yale University, New Haven, Connecticut 06520, USA |
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Abstract: | Ultraviolet (266 nm) and visible (532 nm) photodissociation of collision-free s-tetrazine show asymmetric dynamics with production of one translationally cool and one translationally hot HCN molecule. Furthermore, visible and ultraviolet dynamics are nearly identical, arguing that two-photon excitation is necessary for photodissociation in the visible. |
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Keywords: | On leave present address Radiation Physics Division National Bureau of Standards Washington D.C. 20234 USA. |
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