The role of reagent internal excitation in collision experiments |
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| Authors: | A Ben-Shaul RD Levine |
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| Institution: | Department of Physical Chemistry, The Hebrew University, Jerusalem, Israel |
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| Abstract: | Variations in the rates of endoergic reactions due to different reagent excitations at the same total energy are of a limited (positive or negative) range and reflect a dynamical bias. Not so for bulk experiments, where all non-selected degrees of freedom have a thermal distribution. |
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