Paramagnetic resonance of interstitial mo5+ in a tio2 lattice |
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Authors: | P Meriaudeau |
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Institution: | Laboratoire de Catalyse Appliquée et Cinétique Hétérogène de I''Université Claude Bernard (Lyon I) associé au CNRS (L.A. No. 231), 69622 Villeurbanne Cedex, France |
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Abstract: | Paramagnetic absorption of Mo5+ has been studied in a polycrystalline TiO2 rutile lattice, The g tensor (gx = 1.897, gy = 1.920, gz = 1.857) and the hyperfine tensor (Ax = 32.7, (Ay = 51.2, (Az = 58.5 (in 10?4 cm?1)) are in agreement with those expected for an nd1 ion in an interstitial position. |
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