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Restricted intramolecular vibrational relaxation in polyatomics and laser selective effects
Authors:Everett Thiele  Myron F. Goodman  James Stone
Affiliation:Department of Biological Sciences and Center for Laser Studies, University of Southern California, Los Angeles, California 90007, USA
Abstract:A theory for unimolecular dissociation applicable to selective laser excitation is presented. Expressions for lifetimes, yields, and product fragment translational energy distributions are given as a function of IVR rate. We analyze an experiment purporting to “ demonstrate” rapid IVR.
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