Laser photolysis studies on intramolecular exciplex systems of benzophenone and N,N-dimethylaniline |
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Authors: | Hiroshi Masuhara Yasuhiro Maeda Noboru Mataga Kyoichi Tomita Hitoshi Tatemitsu Yoshiteru Sakata Soichi Misumi |
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Affiliation: | Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka 560, Japan;The Institute of Scientific and Industrial Research, Osaka University, Suita, Osaka 565, Japan |
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Abstract: | Photoprimary processes of intramolecular exciplex systems of benzophenone and N,N-dimethylaniline were studied by means of laser spectroscopy. Electron transfer in acetonitrile and hydrogen abstraction in benzene occur quite rapidly almost independent of the number of methylene chain connecting both moieties, which indicates that a definite and restricted structure is not necessary for both processes. |
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