Interpretation of the vibronic fine structure in the fluorescence spectrum of matrix isolated UF6 |
| |
| Authors: | Joseph M Grzybowski Marek Z Zgierski |
| |
| Institution: | Division of Chemistry, National Research Council of Canada Ottawa, Canada KI4 OR6 |
| |
| Abstract: | The emission spectra of UF6 in an argon matrix are ascribed to a T1g state subject to a strong Jahn-Teller effect and a weak crystal field and Herzberg-Teller effects. These effects account quantitatively for the observed triplet structure of the vibronic bands without involving different crystal sites. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
