Four-photon resonant multiphoton ionization spectroscopy |
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Authors: | Ruth McDiarmid A. Auerbach |
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Affiliation: | Laboratory of Chemical Physics, National Institute of Arthritis, Metabolism and Digestive Diseases, National Institutes of Health, Bethesda, Maryland 20205, USA |
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Abstract: | Resonant multiphoton lonization (MPI) has been found to the red of the lowest energy three-photon resonant MPI band of butadiene. The signal arises from four-photon resonant MPI with an estimated cross section of 10?115-2-10?118 cm8 s3. The observed resonance is deduced to arise from a succession of one-photon allowed transitions. |
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