The vibrational population inversion and relaxation kinetics of the C*2, d 3Πg state |
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| Authors: | Li Xuechu Lou Nanquan |
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| Institution: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, People''s Republic of China |
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| Abstract: | The chemiluminescent spectra of C*2, d 3Πg-a 3Πu, Δv = O sequence from the reaction Na + CCl4 have been obtained. The C*2, d 3Πg,v' = 6 level is formed preferentially. The quenching and vibrational relaxation rates of the C*2, d 3Πg state in Ar are 1.9 × 106 and 2.2 × 106 Torr?1 s?1, respectively. Na is one of the most efficient species for deactivation of C*2. |
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