Dual luminescences in [W(Cp)(CO)3]2 and [Mo(Cp)(CO)3]2 |
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| Authors: | C.G. Morgante W.S. Struve |
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| Affiliation: | Department of Chemistry and Ames Laboratory -USDOE, Iowa State University, Ames, Iowa 50011, USA |
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| Abstract: | Cyclohexane solutions of [W(Cp)(CO)3]2 and [Mo(Cp)(CO)3]2 exhibit weak bimodal emission spectra when excited With 354 nm picosecond pulses, but do not luminesce when pumped at 530 nm. Picosecond lifetimes characterize the short-wavelength, emission bands, which may originate from metal-cyclopentadienyl CT excited states. |
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