Collisional relaxation Of HF(v = 3,4) By HF,CH4 and CD4 |
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| Authors: | JK Lampert GM Jursich FF Crim |
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| Institution: | Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA |
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| Abstract: | Direct excitation of overtone vibrations in combination with near-infrared fluorescence detection provides collisional relaxation rate constants for HF(v = 3,4) by HF, CH4 and CD4. Observing fluorescence from a few rotational levels shows that the rotational manifold in HF(v = 4) equilibrates in about half the gas kinetic collision time. |
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