Laser raman spectra of the stable low-temperature phase of ferrocene |
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Authors: | Michio Sorai Shigemi Murkawa Kouji Ogasahara Hiroshi Suga |
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Affiliation: | Department of Chemistry and Chemical Thermodynamics Laboratory, Faculty of Science, Osaka University Toyonaka, Osaka 560, Japan |
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Abstract: | Laser Raman spectra of ferrocene crystal are recorded for the stable (orthorhombic) and metastable (triclinic) low-temperature phases, and the stable and undercooled (monoclinic) high-temperature phases.The skeletal vibrational modes [v4(A1g) and v16(E1g)], the CH bending (⊥e) mode [v25(E2g)], and the lattice modes below 100 cm?1 show characteristic changes among these phases. |
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Keywords: | Present address: Integrated Circuit Section Sharp Corporation Tenri Nara 632 Japan. |
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