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Laser raman spectra of the stable low-temperature phase of ferrocene
Authors:Michio Sorai  Shigemi Murkawa  Kouji Ogasahara  Hiroshi Suga
Institution:Department of Chemistry and Chemical Thermodynamics Laboratory, Faculty of Science, Osaka University Toyonaka, Osaka 560, Japan
Abstract:Laser Raman spectra of ferrocene crystal are recorded for the stable (orthorhombic) and metastable (triclinic) low-temperature phases, and the stable and undercooled (monoclinic) high-temperature phases.The skeletal vibrational modes v4(A1g) and v16(E1g)], the CH bending (⊥e) mode v25(E2g)], and the lattice modes below 100 cm?1 show characteristic changes among these phases.
Keywords:Present address: Integrated Circuit Section  Sharp Corporation  Tenri  Nara 632  Japan  
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