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Valence fluctuation in some Yb intermetallics by X-ray photoemission and X-ray absorption |
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| Authors: | C.N.R. Rao D.D. Sarma P.R. Sarode E.V. Sampathkumaran L.C. Gupta R. Vijayaraghavan |
| Affiliation: | Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India;Tata Institute of Fundamental Research, Bombay 400005, India |
| Abstract: | The valence state of Yb in some of its intermetallics, YbNi2Ge2, YbCu2Si2 and YbPd2Si2 has been investigated by LIII(Yb) absorption edges and X-ray pnotoelectron spectra in the 4f and 4d regions. These studies establish the presence of mixed valence in all three systems and illustrate the utility of 4f and 4d spectra in the study of mixed valence in Yb compounds. |
| Keywords: | Present address: Fachbereich 9 Physikalische Chemie Gesamthochschule Wuppertal 56 Wuppertal 1 Germany. |
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