Non-condon effects on radiationless triplet decay in benzene and naphthalene |
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Authors: | Willem Siebrand Marek Z Zgierski |
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Institution: | Division of Chemistry National Research Council of Canada, Ottawa, Canada KIA OR6 |
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Abstract: | Model calculations that avoid the Condon approximation are reported for T1ar S0 intersystem crossing in normal and perdeuterated benzene and naphthalene. In both benzenes and in naphthalene-d8, skeletal bending vibrations coupling T1 to T2 are found to be more efficient as accepting modes than CH-stretching vibrations. |
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