Excited quintet states during the photopolymerization of diacetylene single crystals |
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| Authors: | R Huber M Schwoerer |
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| Institution: | Lehrstuhl fur Experimentalphysik II Universitat Bayreuth, D-8580 Bayreuth, Germany |
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| Abstract: | During the photopolymerization of perdeuterated PTS diacetylene single crystals at low temperatures, excited quintet states (S = 2) are observed Nine ESR transitions per quintet were detected. They are analyzed in terms of a spin hamiltonian for S = 2. They are due to bicarbenes of, probably, short oligomers. |
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