Excitation energy effects in the photophysics of trans-stilbene in solution |
| |
Authors: | F.E. Doany B.I. Greene R.M. Hochstrasser |
| |
Affiliation: | Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA |
| |
Abstract: | Excitation of trans-stilbene with 306 nm pulses generates a narrower transient spectrum than with 265 nm. These spectra do not evolve in the same manner, suggesting that the spectral changes with 265 nm result from vibrational cooling. Spectral differences at longer times suggest there is a slow cross-relaxation component in the inhomogeneous distribution. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |