Absorption spectrum and kinetics of the acetylperoxy radical |
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| Authors: | M.C. Addison J.J. Burrows R.A. Cox R. Patrick |
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| Affiliation: | Environmental and Medical Sciences Division, A.E.R.E., Harwell, Oxfordshire, UK |
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| Abstract: | The UV absorption spectrum of acetylperoxy radicals, produced in several photochemical systems, has been investigated using the molecular modulation technique. Rate coefficients were determined at 28 and 715 Torr for the reaction CH3COO2 + NO2(+M) → CH3COO2NO2(+M), which exhibits a pressure dependence. |
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