23Na NMR study of ionic mesophases in molten sodium carboxylates |
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| Authors: | J Bonekamp T Eguchi J Jonas |
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| Institution: | Department of Chemistry, School of Chemical Sciences, University of Illinois, Urbana, Illinois 61801, USA |
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| Abstract: | The 23Na NMR lineshapes are reported for the ionic mesophase and isotropic phase of the melts of sodium n-butyrate and sodium isovalerate. The powder pattern for the central transition typical for the second-order quadrupole effect observed in the mesophase melts is of particular interest. Some analogies to 23Na behavior in sodium β-alumina are pointed out. |
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| Keywords: | Permanent address: Institute of Chemistry College of General Education Osaka University Toyonaka Osaka 560 Japan |
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