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Interaction of bis(trimethylsilyl)acetylene complex of titanocene with mercury trifluoroacetate |
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| Authors: | L I Strunkina M Kh Minacheva K A Lyssenko Z S Klemenkova A Yu Volkonsky P V Petrovskii V V Burlakov V B Shur |
| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
| Abstract: | The reaction of the bis(trimethylsilyl)acetylene complex of titanocene Cp2Ti(Me3SiC2SiMe3) with mercury trifluoroacetate (NF3COO)2Hg at 20 °C in a THF medium affords titanocene bis(trifluoroacetate) Cp2Ti(OCOCF3)2 and metallic mercury. The structure of Cp2Ti(OCOCF3)2 was established by the analytical and spectroscopic methods and X-ray diffraction analysis. |
| Keywords: | acetylene complexes of titanocene mercury trifluoroacetate trifluoroacetate complexes X-ray diffraction analysis |
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