Novel bis(ethylenedithio)tetrathiafulvalene-based organic conductor with 1,1'-ferrocenedisulfonate |
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| Authors: | Akutsu Hiroki Ohnishi Ryo Yamada Jun-ich Nakatsuji Shin'ichi Turner Scott S |
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| Institution: | Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Ako-gun, Hyogo 678-1297, Japan. akutsu@sci.u-hyogo.ac.jp |
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| Abstract: | A new bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based salt with a ferrocenyl moiety, alpha' '-(BEDT-TTF)(4)(Fe(C(5)H(4)SO(3))(2)).6H(2)O, has been prepared. The ferrocenyl part of this salt is neutral and diamagnetic, but the magnetic susceptibility is well modeled by a Curie-Weiss law with C = 0.142 emu.K.mol(-1) (approximately 1/3 of s = 1/2 spin). The spin is likely to be localized on the donor layer because of its unique charge disproportionation. |
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