Total synthesis of (+)-strictifolione |
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Authors: | BouzBouz Samir Cossy Janine |
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Institution: | Laboratoire de Chimie Organique Associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris, Cedex 05, France. |
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Abstract: | reaction: see text] The synthesis of (+)-strictifolione was achieved from 3-phenylproprionaldehyde by using enantioselective allyltitanations to control the stereogenic centers at C6, C4', and C6' and a cross-methathesis to control the configuration of the double bond at C1'-C2'. |
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