A stereoselective enyne cross metathesis |
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| Authors: | Lee Hee-Yoon Kim Byung Gyu Snapper Marc L |
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| Affiliation: | Center for Molecular Design & Synthesis, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science & Technology, Daejon 305-701, Korea. |
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| Abstract: | [reaction: see text] Intermolecular enyne metathesis reaction of alkynes with olefins catalyzed by second-generation Grubbs catalyst (1) proceeded stereoselectively under ethylene atmosphere to produce 1,3-disubstituted butadienes with E stereochemistry. |
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