Enantioselective synthesis of allenyl carbinols by the CBS reduction in nitroethane: dramatic solvent effect for reactivity and enantioselectivity |
| |
| Authors: | Yu Chan-Mo Kim Chunsan Kweon Jae-Hong |
| |
| Affiliation: | Department of Chemistry and Lab for Metal-Catalysed Reactions, Sungkyunkwan University, Suwon, 440-746, Korea. cmyu@chem.skku.ac.kr |
| |
| Abstract: | Dramatic solvent effect of nitroethane was observed in the catalytic asymmetric reductions of allenyl ketones and alpha,beta-ynones using the oxazaborolidine cayalyst to yield the corresponding alcohols in high levels of enantioselectivity. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
