Evidence for magnetic anisotropy of [Nb(IV)(CN)8]4- in a pillared-layered Mn2Nb framework showing spin-flop transition |
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| Authors: | Pinkowicz Dawid Rams Micha? Nitek Wojciech Czarnecki Bernard Sieklucka Barbara |
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| Institution: | Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland. pinkowic@chemia.uj.edu.pl |
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| Abstract: | The first example of the Nb(CN)(8)]-based pillared-layered-type framework system {Mn(II)(2)(bpdo)(H(2)O)(4)]Nb(IV)(CN)(8)]·6H(2)O}(n) (bpdo = 4,4'-bipyridyl-N,N'-dioxide) has been obtained and characterized structurally and magnetically. The presented results provide the first evidence for substantial magnetic anisotropy of Nb(IV)(CN)(8)]. |
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