Titan(IV)-Komplexe mit dreizähnigen diaciden Liganden. Kristallstruktur von Bis[2,6-diphenacylpyridinato(2 –)]titan(IV) |
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Authors: | H. Hefele,E. Ludwig,E. Uhlemann,H. N th |
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Affiliation: | H. Hefele,E. Ludwig,E. Uhlemann,H. Nöth |
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Abstract: | Titanium(IV) Complexes with Tridentate Diacidic Ligands. Crystal Structure of Bis[2,6-diphenacylpyridinato(2–)]titanium(IV) The titanium(IV) chelates with 2,2′-dihydroxy-azobenzene, salicylaldehyde-2-hydroxyanil, 2-(2′-hydroxyphenyl)-8-quinolinol, 2,6-diphenacylpyridine as well as with aroylhydrazones of salicylaldehyde, benzoylacetone and thenoyltrifluoroacetone were synthesized by ligand exchange reactions of titanium(IV)-isopropoxide. The compounds are red or black in colour and were identified by distinct molecular peaks in the mass spectra. The crystal and molecular structure was determined for bis[2,6-diphenacylpyridinato(2–)] titanium(IV). Crystallographic data see “Inhaltsübersicht”. |
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Keywords: | Titanium(IV) Chelates Tridentate Diacidic Ligands Mass Spectra, Charge Transfer Band, Structure of Bis[2,6-diphenacylpyridinato(2– )]titanium(IV) |
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