Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. 63. Darstellung und Kristallstruktur von Tetramethyltitan-tetrahydrofuran |
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| Authors: | H. Windisch,K.-H. Thiele,G. Kociok-K hn,H. Schumann |
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| Affiliation: | H. Windisch,K.-H. Thiele,G. Kociok-Köhn,H. Schumann |
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| Abstract: | Contributions to the Chemistry of Transition Metal Alkyl Compounds. 63. Preparation and Crystal Structure of Tetramethyltitanium Tetrahydrofuran Me4Ti · 2THF 1 dissoziates partially in n-pentane. The formed Me4Ti · THF 2 could be isolated. According to X-ray structure determination the molecules of 2 have a trigonalbipyramidal shape with the THF molecule in axial position. |
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| Keywords: | Tetramethyltitanium tetrahydrofuran crystal structure |
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