Ethers as ligands. Part V(1). Metal(II)-diglyme and -pentaglyme solvates |
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| Authors: | Willem L Driessen Marinus den Heijer Nico van Gils Willem L Groeneveld |
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| Institution: | (1) Gorlaeus Laboratories of the State University of Leiden, P. O. Box 9502, 2300 RA Leiden, The Netherlands |
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| Abstract: | Summary Eighteen new coordination compounds are reported with diglyme (dgm) and pentaglyme (pgm) as ligands:viz. M(dgm)2](SbCl6)2 with M=MgII, CaII, SrII, MnII, FeII, CoII, NiII, CuII, and ZnII; M(pgm)](SbCl6)2 with M=MnII, FeII,CoII, NiII, CuII, and ZnII; and M(pgm)](SbCl6)2 · H2O with M=MgII, CaII, and SrII. The metal(II) ions are hexacoordinated by the ether-oxygens of two diglyme molecules or of one pentaglyme molecule. The coordinated diglyme molecules are in the TGTT¯GT conformation. |
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