Investigation of the catalytic properties of platinum-tin complexes containing dimethyl sulfoxide,dimethylformamide, or dimethylacetamide |
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| Authors: | N V Borunova P G Antonov Yu N Kukushkin Ya G Mukhtarov A N Shan'ko L Kh Freidlin |
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| Institution: | (1) Department of Chemistry and Biochemistry, University of Wisconsin-Milwaukee, Milwaukee, WI 53211, USA |
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| Abstract: | | 1. |
The catalytic activity of new complexes of Pt (II)-Sn (II) with dimethylacetamide and DMF in isomerization and hydrogenation reactions of compounds containing a C=C bond is greater than the activity of the Pt-SnCl3 complex by a factor of 4–5.
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All the examined complexes catalyzed the selective hydrogenation of phenylacetylene to styrene, and diphenylacetylene to diphenylethane passing through the stilbene stage.
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