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Clathrates of organic onium halides,V: preparation of new clathrates and structure of the 1-propanol inclusion of a bis-quinuclidinium salt
Authors:Hans-Peter Josel  Hans-Gerd Löhr  Aloys Engel  Jochen Rapp  Fritz Vögtle  Sybille Franken  Heinrich Puff
Institution:(1) Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300 Bonn 1, West Germany;(2) Anorganisch-Chemisches Institut der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300 Bonn 1, West Germany
Abstract:Organic onium salts (3–15) are prepared and their inclusion capacity towards solvent molecules is investigated. The crystal structure of the1·propanol·H2O clathrate ofN,Nprime-5-tert-butyl-1,3-phenylenebis(methylene)]bis(quinuclidinium)dibromide (4) is reported and compared with the X-ray structures of related clathrates described earlier. Supplementary Data: Details of the crystal structure are available on request from the Fachinformationszentrum Energie-Physik-Mathematik, D-7517 Eggenstein, Leopoldshafen 2, by quoting the depository number CSD 50883, the names of the authors, and the journal citation.
Keywords:Inclusion  clathrate  clathrand  host/guest  X-ray analysis  ammonium compounds  phosphonium compounds  quinuclidinium derivative
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