Clathrates of organic onium halides,V: preparation of new clathrates and structure of the 1-propanol inclusion of a bis-quinuclidinium salt |
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Authors: | Hans-Peter Josel Hans-Gerd Löhr Aloys Engel Jochen Rapp Fritz Vögtle Sybille Franken Heinrich Puff |
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Institution: | (1) Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300 Bonn 1, West Germany;(2) Anorganisch-Chemisches Institut der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300 Bonn 1, West Germany |
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Abstract: | Organic onium salts (3–15) are prepared and their inclusion capacity towards solvent molecules is investigated. The crystal structure of the1·propanol·H2O clathrate ofN,N -5-tert-butyl-1,3-phenylenebis(methylene)]bis(quinuclidinium)dibromide (4) is reported and compared with the X-ray structures of related clathrates described earlier.
Supplementary Data: Details of the crystal structure are available on request from the Fachinformationszentrum Energie-Physik-Mathematik, D-7517 Eggenstein, Leopoldshafen 2, by quoting the depository number CSD 50883, the names of the authors, and the journal citation. |
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Keywords: | Inclusion clathrate clathrand host/guest X-ray analysis ammonium compounds phosphonium compounds quinuclidinium derivative |
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