Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers |
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Authors: | Lewiński Janusz Kaczorowski Tomasz Justyniak Iwona Prochowicz Daniel |
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Affiliation: | Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland. lewin@ch.pw.edu.pl |
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Abstract: | The bimetallic chiral bipyridyl-type metalloligands based on aluminium derivatives of cinchonine, [R(2)Al(μ-CN)](2) (R = Me or Et), in combination with the corresponding ZnR(2) compound as nodes were used for the generation of novel homochiral heterometallic coordination polymers of either zig-zag or helical topology, depending on the character of the R substituent. |
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