A novel thermal rearrangement of N-cyano-N-(α-cyanobenzhydryl)-aniline |
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Authors: | Gy. Simig K. Lempert L. Imre J. Tamas |
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Affiliation: | Research Group for Alkaloid Chemistry of the Hungarian Academy of Sciences, 1111-Budapest XI., Gelle´rt te´r 4., Hungary;Central Research Institute fu¨r Chemistry of the Hungarian Academy of Sciences, Budapest Hungary |
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Abstract: | The title compound1 is rearranged, when refluxed with toluene, to the carbodiimide5 and the cyanoaniline7. While rearrangements analogous to the transformation1→5 have recently been observed, the transformation1→7 is novel. |
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